Coupling of manometric, calorimetric and residual gas analysis measurements to probe sorption parameters of tritium storage systems

The gas sorption Sievert’s technique has proven to have many advantages over the other techniques for the evaluation of the ad/ab-sorbed amount of gas by the materials in a wide range of temperature and pressure. In addition, there is a total freedom in the size and shape of the sample holder in the volumetric technique, enabling the coupling of techniques and insitu measurements of various chemical and physical parameters. The presented system is a coupled system with volumetric technique, calorimetry and high resolution mass spectrometry. This paper will give an overview of the state-of-the art possibility of combined manometric – calorimetric analysis with RGA and a highlight on the tritium applications that this combination permits to analyze. A case study with hydrogen is taken to illustrate a typical experiment